HW1

McMurry HW Ch 1: Prob 23ac, 24, 26, 42, 45 麦克默里(McMurry)作业第1章:习题23ac, 24, 26, 42, 45

Q1

PROBLEM 1-23 Give the ground-state electron configuration for each of the following elements: 问题 1-23 给出下列各元素的基态电子构型:

(a) Potassium (a) 钾

(c) Aluminum (c) 铝

Q2

PROBLEM 1-24 What are likely formulas for the following molecules? 问题 1-24 下列分子的可能分子式是什么?

(a) NH?OH\mathrm{NH}_{?} \mathrm{OH} (a) NH?OH\mathrm{NH}_{?} \mathrm{OH}

(b) AlCl\mathrm{AlCl}_{\text {? }} (b) AlCl\mathrm{AlCl}_{\text {? }}

(c) CF2Cl\mathrm{CF}_{2} \mathrm{Cl} ? (c) CF2Cl\mathrm{CF}_{2} \mathrm{Cl} ?

(d) CH?O\mathrm{CH}_{?} \mathrm{O} (d) CH?O\mathrm{CH}_{?} \mathrm{O}

Q3

PROBLEM 1-26 Draw an electron-dot structure for acetonitrile, C2H3 N\mathrm{C}_{2} \mathrm{H}_{3} \mathrm{~N}, which contains a carbon-nitrogen triple bond. How many electrons does the nitrogen atom have in its outer shell? How many are bonding, and how many are nonbonding? 问题 1-26 绘制乙腈(C2H3 N\mathrm{C}_{2} \mathrm{H}_{3} \mathrm{~N})的电子点结构,该分子含有一个碳-氮三键。氮原子在其外层有多少个电子?其中有多少个是成键电子,又有多少个是非成键电子?

Q4

PROBLEM 1-42 How many hydrogens are bonded to each carbon atom in the following substances, and what is the molecular formula of each? 问题 1-42 下列物质中,每个碳原子连接了多少个氢原子?每种物质的分子式是什么?

1758101195694

Q5

PROBLEM 1-45 Why do you suppose no one has ever been able to make cyclopentyne as a stable molecule? 问题 1-45 您认为为什么没有人能够制备出稳定的环戊炔分子?

1758101251155